Monday, July 11, 2011

Balance the ionic equation by half reaction method O3+ Br- -------> O2 + BrO-



Answer:-

Step -1  
       Find the oxidation number of Br in BrO-
       in combination state oxygen has oxidation number = - 2 
             Br + O = - 1 
               Br -2 = -1 
                   Br = +1  

Step -2 
        write oxidation half reaction 

               Br-  <-----------> BrO- 
               -1                       +1
       here oxidation number of Br is increasing by 2 
       so add 2 electron to balance it 

       we get 
              Br-  <-----------> BrO-   + 2e-             
Step -3 

add OH - ions to balance the charge reaction 

Br- +  2OH-   <----------->BrO-   + 2e
Step - 4 
add H2O to balance the hydrogen and oxygen 

Br- +  2OH-   <----------->BrO-   +H2O +  2e 

balanced oxidation half reaction

 Br- +  2OH-   <----------->BrO-   +H2O +  2e   ---------------(1)

similarly you can get balanced half reduction reaction 

Balanced reaction half reaction 
O3 + H2O + 2 e- <-----------> O2 + 2 OH-        ---------------(2)

add both equations we get 


Br- +  2OH-  + O3 + H2O + 2 e- <-----------> BrO-   + 2e + O2 + 2 OH-
simplify the equation we get

O3+  Br- <----------->O2 +  BrO-

Answer : -  Equation was already balanced 



Balance the ionic equation
Balance the ionic equation



1 comment: